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رویکردی مفهومی به پیوند هیدروژنی | ||
| پژوهش در آموزش شیمی | ||
| مقاله 9، دوره 8، شماره 3 - شماره پیاپی 31، مهر 1405، صفحه 1-26 اصل مقاله (1.35 M) | ||
| نوع مقاله: مقاله مروری | ||
| شناسه دیجیتال (DOI): 10.48310/chemedu.2025.18759.1316 | ||
| نویسنده | ||
| ابراهیم زارعی کیاسری* | ||
| گروه آموزش شیمی، دانشگاه فرهنگیان، صندوق پستی ۱۴۶۶۵-۸۸۹، تهران، ایران | ||
| چکیده | ||
| پیشینه و اهداف: علیرغم اینکه مفهوم پیوند هیدروژنی بیش از یک قرن است که نه تنها در شیمی بلکه در سایر شاخههای علم نیز مورد استفاده قرار میگیرد، هنوز در مورد معنای این اصطلاح اساسی بحثی وجود دارد. با توجه به اهمیت پیوند هیدروژنی و نتایج تجربی اخیر مشاهده شده، در این بررسی سعی شده است جنبههای جالب مفهوم پیوند هیدروژنی که کمتر در کتابهای درسی به آن پرداخته شده است، مورد بحث قرار گیرد. امید است این بحث برای معلمان و دانش آموزان شیمی مفید باشد. روشها: این مطالعه به روش کتابخانهای و با استفاده از پایگاههای اطلاعاتی معتبر علمی مانند گوگل اسکولار انجام شد. در این مطالعه، تلاشی برای بررسی اطلاعات جمعآوریشده و ارائه دیدگاهی ثابت در مورد تعریف پیوند هیدروژنی، دستهبندیهای آن و جنبههای مرتبط انجام شد. یافتهها: با مطالعه دقیق، یک تعریف عملی از پیوند هیدروژنی به دست آمده است. علاوه بر این، گزارشهای مختلف در مورد پیوند هیدروژنی نشان میدهد که این پیوند نه تنها با اتمهای نیتروژن، اکسیژن و فلوئور، بلکه در شرایط خاص، بین سایر اتمها مانند بور، کربن و حتی خود هیدروژن نیز میتواند تشکیل شود. بخشهای بعدی به بحث در مورد پیوندهای هیدروژنی متقارن و نتایج محاسبات شیمیایی کوانتومی مربوط به این موضوع اختصاص دارد. نتیجهگیری: این تحقیق با تمرکز بر تعریف مجدد پیوند هیدروژنی، مروری جامع در مورد این موضوع با توجه خاص به پیوند هیدروژنی متقارن ارائه میکند. با توجه به اطلاعات گسترده موجود در مورد پیوند هیدروژنی، این مقاله قصد دارد، جنبههای خاصی از این پیوند عجیب و غریب را روشن کند. توصیه میشود که از محاسبات شیمیایی کوانتومی برای بررسی بیشتر پیوند هیدروژنی استفاده شود تا درک عمیقتر و کاملی از این پیوند شیمیایی پیچیده به دست آید. | ||
| کلیدواژهها | ||
| تعریف کاربردی پیوند هیدروژنی؛ عوامل مؤثر بر قدرت پیوند هیدروژنی؛ پیوند هیدروژنی متقارن؛ ' محاسبات کوانتمی شیمی؛ ' پیوند هیدروژنی عناصر کم الکترونگاتیو؛ ' عناصر بور؛ کربن و هیدروژن | ||
| عنوان مقاله [English] | ||
| A conceptual approach to hydrogen bonding | ||
| نویسندگان [English] | ||
| Ebrahim Zarei Kiasari | ||
| Department of Chemistry Education, Farhangian University, P.O. Box 14665-889, Tehran, Iran | ||
| چکیده [English] | ||
| Background and Objective: In spite of the fact that the concept of hydrogen bond has been used not only in chemistry but also in other branches of science for more than a century, there is still some doubt about what this basic term means. Due to the importance of hydrogen bond and lately observed experimental results, an attempt has been made to discuss interesting aspects of the hydrogen bonding concept in this review paper, which are not elaborated upon properly in the textbooks. Hopefully, this study will be beneficial for chemistry teachers and students. Materials and Methods: This study was carried out based on literature survey using reliable scientific databases, such as Google Scholar. In this study, an effort was undertaken to examine the collected data and present a consistent perspective on the definition of hydrogen bond, its categories, some and related aspects. Findings: A practical definition of hydrogen bonding was obtained by a careful review of the literature. In addition, the various reports about hydrogen bond indicate that it can form not only with nitrogen, oxygen, and fluorine atoms but also, under specific conditions, with other atoms such as boron, carbon, and even hydrogen itself. Subsequent sections are devoted to the discussion of symmetric hydrogen bonds and the results of quantum chemical calculations related to this topic. Conclusion: This research, focusing on redefinition of the hydrogen bond, offers a comprehensive review about this subject with a special focus on the symmetric hydrogen bond. Regarding the vast information available on hydrogen bond, this article aims to shed light on certain aspects of this peculiar bond. It is recommended that quantum chemical calculations should be used to further investigate hydrogen bond in order to get a deeper and thorough understanding of this intricate chemical bond. | ||
| کلیدواژهها [English] | ||
| Practical definition of hydrogen bond, Factors affecting hydrogen bond strength, Symmetric hydrogen bond, Quantum chemical calculations, Hydrogen bonding of less electronegative elements, Boron, carbon and hydrogen elements | ||
| مراجع | ||
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